In recent months, substantial progress has been made in complex reasoning of Large Language Models (LLMs), particularly through the application of test-time scaling. Notable examples include, though are not limited to, OpenAI's o1/o3/o4 series and DeepSeek-R1. When responding to a query, these models generate an extended reasoning trajectory, during which the model explores, reflects, backtracks, and self-verifies before arriving at a conclusion. However, fine-tuning models with such reasoning trajectories may not always be optimal. Our findings indicate that not all components within these reasoning trajectories contribute positively to the reasoning process; in fact, some components may affect the overall performance negatively. In this study, we divide a reasoning trajectory into individual subtrajectories and develop a "5+2" framework to: (1) systematically identify suboptimal subtrajectories within the reasoning trajectory based on five human-established criteria; (2) assess the independence of the suboptimal subtrajectories identified in (1) from the subsequent content, ensuring that their elimination does not compromise overall flow and coherence of the reasoning process. Additionally, a sampling algorithm, built upon the "5+2" framework, is employed to select data whose reasoning process is free from suboptimal subtrajectories to the highest degree. Experimental results demonstrate that our method can reduce the number of suboptimal subtrajectories by 25.9\% during the inference. Furthermore, our method achieves an average accuracy of 58.92\% on highly challenging AIME24, AIME25, AMC24 and MATH500 benchmarks with only two thirds of training data, surpassing the average accuracy of 58.06\% achieved with the entire data, and outperforming open-source datasets, including s1K-1.1, Light-R1-SFT-stage-1, OpenR1-Math-94k, and OpenThoughts-114k, when fine-tuning Qwen2.5-Math-7B. Finally, we have validated the efficacy of our method under resource-constrained scenarios, where it exhibits performance improvements across different maximum inference token limits: 2k, 4k, 8k, and 16k tokens.