Multi-modal knowledge graph completion (MMKGC) aims to infer missing entities of triples by leveraging heterogeneous information in knowledge graph (KG). However, existing approaches often struggle with inconsistent modality alignment, limited reasoning depth, and insufficient negative sample quality. In this work, we propose HFR-MKGC, a novel framework that integrates hierarchical modal fusion and Multimodal Large Language Model (MLLM) reasoning for robust and expressive MMKGC. Specifically, we introduce a relation-guided hierarchical modal fusion module, which conducts fine-grained intra-visual fusion and relation-guided cross-modal integration to yield rich entity representations. HFR-MKGC employs a fine-tuned MLLM to perform instruction-based triple reasoning, producing candidate entities for completion. Then, it constructs hard negative samples through textual perturbation by MLLM and visual feature augmentation with rotation and noise.HFR-MKGC optimizes the model via adversarial training. Extensive experiments on three MMKGC benchmarks demonstrate that our method outperforms state-of-the-art methods, validating its effectiveness in MMKGC.