Large language models (LLMs) generate high-dimensional embeddings that capture rich semantic and syntactic information. However, high-dimensional embeddings exacerbate computational complexity and storage requirements, thereby hindering practical deployment. To address these challenges, we propose a novel training framework named Sequential Matryoshka Embedding Compression (SMEC). This framework introduces the Sequential Matryoshka Representation Learning(SMRL) method to mitigate gradient variance during training, the Adaptive Dimension Selection (ADS) module to reduce information degradation during dimension pruning, and the Selectable Cross-batch Memory (S-XBM) module to enhance unsupervised learning between high- and low-dimensional embeddings. Experiments on image, text, and multimodal datasets demonstrate that SMEC achieves significant dimensionality reduction while maintaining performance. For instance, on the BEIR dataset, our approach improves the performance of compressed LLM2Vec embeddings (256 dimensions) by 1.1 points and 2.7 points compared to the Matryoshka-Adaptor and Search-Adaptor models, respectively.